Table 4: The UV-Vis data and their assignments for L1, L2 and their complexes.


Compound UV-Vis data (nm) Assignment

ππ nπ d−d/CT

 L1 258 325
 Fe (1) 269 349
 Ni (2) 260 333
 Cu (3) 264 314 368 CT
 L2 275 365
 Fe (4) 258 348 439 CT
 Ni (5) 259 339 431 1A2g1A1g
 Cu (6) 285 334 441 2B2g2B1g