Table 3: IR spectra data of the Schiff bases ligands and their metal complexes (1)–(6).


Compound IR data (cm−1)

ν(OH) νν(CH⚌N)SB ν(M─N)

L1     1680 (S)
 [Fe(L1)2Cl3]2H2O (1) 3343 (W) 1686 (S) 415 (W)
 [Ni(L1)2Cl2]2H2O (2) 3344 (W) 1686 (S) 419 (W)
 [Cu(L1)2Cl2] (3) 1679 (S) 417 (W)
L2     1673 (S)
 [Fe(L2)2Cl3] (4) 1679 (S) 429 (W)
 [Ni(L2)2Cl2] (5) 1681 (S) 419 (W)
 [Cu(L2)2Cl2] (6) 1677 (S) 411 (W)