Table 2: Elemental analysis and magnetic moment of the ligands L1, L2 and their complexes.


Compound Cal. (found)% μeff (BM)

C H N Cl

L1     76.66
(76.16)
6.81
(6.74)
10.52
(10.48)
 [Fe(L1)2Cl3]2H2O (1) 55.87
(55.33)
5.52
(5.44)
7.67
(7.44)
14.55
(14.37)
4.98
 [Ni(L1)2Cl2]2H2O (2) 58.48
(58.69)
5.77
(7.27)
8.02
(8.17)
10.15
(10.41)
 [Cu(L1)2Cl2] (3) 61.21
(61.23)
5.44
(5.93)
8.40
(8.22)
10.63
(10.98)
1.91
L2     72.07
(71.91)
6.05
(5.01)
4.94
(4.81)
 [Fe(L2)2Cl3] (4) 56.03
(55.98)
4.70
(4.37)
3.84
(3.81)
14.59
(14.68)
5.21
 [Ni(L2)2Cl2] (5) 58.65
(68.59)
4.92
(4.49)
4.02
(4.01)
10.18
(9.99)
 [Cu(L2)2Cl2] (6) 58.25
(59.61)
4.89
(4.64)
4.00
(4.07)
10.11
(10.17)
1.84