Table 1: Some physical parameters of the ligands L1, L2 and their complexes.


Compound Molecular formula M.wt. (g/mol) Color m.p. (°C)

L1    C17H18N2O 266.34 yellow 135
 [Fe(L1)2Cl3]2H2O (1)  C34H40Cl3N4O4Fe 730.91 orange > 300
 [Ni(L1)2Cl2]2H2O (2)  C34H40Cl2N4O4Ni 698.30 orange > 300
 [Cu(L1)2Cl2] (3)  C34H36Cl2N4O2Cu 667.13 brown > 300
L2    C17H17NO3 283.33 yellow 122
 [Fe(L2)2Cl3] (4)  C34H34Cl3N2O6Fe 728.85 brown > 300
 [Ni(L2)2Cl2] (5)  C34H34Cl2N2O6Ni 696.24 yellow > 300
 [Cu(L2)2Cl2] (6)  C34H34Cl2N2O6Cu 701.09 green > 300