Table 3: Magnetic moments, electronic spectral data, and ligand field parameters of metal complexes.


 Complex μeff (B.M.) Band position (nm) Assignments Dq (cm−1) B0 (cm−1) β ν2/ν1

 [Ti(L)(Cl)(H2O)2] 1.87 532 2T2g2Eg
 [Cr(L)(Cl)(H2O)2] 3.97 580 4A2g4T2g(F) 1,724 709 0.77 1.44
411 4A2g4T1g(F)
262 4A2g4T2g(P)
 [Fe(L)(Cl)(H2O)2] 5.91 833 6A1g4T1g(G)
538 6A1g4T2g(G)
491 6A1g4Eg(D)