Table 3: Magnetic moments, electronic spectral data, and ligand field parameters of metal complexes.
Complex | μeff (B.M.) | Band position (nm) | Assignments | Dq (cm−1) | B0 (cm−1) | β | ν2/ν1 | ||
[Ti(L)(Cl)(H2O)2] | 1.87 | 532 | 2T2g → 2Eg | — | — | — | — | ||
[Cr(L)(Cl)(H2O)2] | 3.97 | 580 | 4A2g → 4T2g(F) | 1,724 | 709 | 0.77 | 1.44 | ||
411 | 4A2g → 4T1g(F) | ||||||||
262 | 4A2g → 4T2g(P) | ||||||||
[Fe(L)(Cl)(H2O)2] | 5.91 | 833 | 6A1g → 4T1g(G) | — | — | — | — | ||
538 | 6A1g → 4T2g(G) | ||||||||
491 | 6A1g → 4Eg(D) | ||||||||