Table 4: The UV-Vis data and their assignments for L1, L2 and their complexes.


 Compound UV-Vis data (nm) Assignment

π–π∗ n–π∗ d−d/CT

 L1 258 325 — —
 Fe (1) 269 349 — —
 Ni (2) 260 333 — —
 Cu (3) 264 314 368 CT
 L2 275 365 — —
 Fe (4) 258 348 439 CT
 Ni (5) 259 339 431 1A2g ← 1A1g
 Cu (6) 285 334 441 2B2g ← 2B1g