Table 4: Microanalytical data, magnetic moment, molar conductance and electronic spectral data of the prepared ternary complexes.
Complexes | M.Wt. | Color | M.P. (°C) | Found (Calcd.) % | μeff/B.M. | ΛMa | λmax/cm−1 | CT | ||
Empirical formula | C | H | N | |||||||
[Co(DPA)(CBDC acid)] | 371.9 | purple | Above 300 | 51.6 | 4.0 | 11.2 | 4.15 | 15.9 | 16,168 | 23,072 |
C16H15N3O4Co | (51.9) | (4.1) | (11.4) | |||||||
[Co(DPA)(malonate)] | 367.9 | purple | 228 | 42.4 | 4.0 | 11.4 | 4.31 | 20.8 | 16,210 | 23,345 |
(H2O)2C13H15N3O6Co | (42.8) | (4.3) | (11.3) | |||||||
[Co(DPA)(oxalate)] | 335.9 | purple | 294 | 42.2 | 3.2 | 12.5 | 4.52 | 17.1 | 15,844 | 23,311 |
(H2O)C12H11N3O5Co | (42.3) | (3.1) | (12.3) | |||||||
[Co(DPA)(succinate)] | 363.9 | purple | 280 | 46.1 | 4.1 | 11.5 | 4.31 | 16.3 | 15,723 | 23,099 |
(H2O)C14H16N3O5Co | (46.3) | (4.2) | (11.3) | |||||||