Table 4: Thermal analyses data of the newly synthesized chelates.


Compound TGA temp. range (°C) DTG temp (°C) Mass loss calcd. % TGA description Residue

C14H7O7NClCr 110–184 134 49.33 (48.64) – The loss of p-chlorophenyl maleanilic acid ligand Cr(CO)2
Cr(CO)4L 185–278 273.5 13.18 (12.13) – The loss of 2CO groups 37.49 (39.23)
C14H7O7NClMo 110–271 190 43.02 (44.42) – The loss of p-chlorophenyl maleanilic acid ligand Mo(CO)4
Mo(CO)4L 57 (55.6)
C14H7O7NClW 131–280 169.69 34.6 (37.17) – The loss of p-chlorophenyl maleanilic acid ligand W(CO)2
W(CO)4L 280–350 252.52 4.33 (4.71) – The loss of CO group 46.09 (44.57)
350–589 391.92 4.64 (4.71) – The loss of CO group