Table 1: Selected bond distances (Å) showing of the ligand constraint-effect.
Complex 1 | Complex 2 | ||
Mn1−O1 | 1.862 | Mn1−O1 | 1.843 |
Mn1−O2 | 1.851 | Mn1−O2 | 1.873 |
Mn1−N1 | 2.105 | Mn1−N1 | 2.166 |
Mn1−N3 | 2.225 | Mn1−N3 | 2.142 |
Mn1−N4 | 2.220 | Mn1−N4 | 2.128 |
Mn1−N6 | 2.128 | Mn1−N6 | 2.173 |
Mn1−Cl | 6.244 | Mn1−NO3 | 4.767 |